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2025-12-24

“intersystem”的英文意思

单词 intersystem
释义 intersystem, a.|ɪntəˈsɪstɪm, -əm|
[f. inter- 5 a + system n.]
Existing between systems; spec. in Physical Chem., between quantized systems or states of different multiplicity. intersystem crossing, the radiationless transition of an excited molecule to a state of different multiplicity.
1915Astrophysical Jrnl. XLI. 326 At the bottom of the table there is a section devoted to ‘inter-system’ series. These..are combinations between the triplet and single-line series.1935Condon & Shortley Theory Atomic Spectra ix. 237 Intersystem combinations are forbidden.1947Chem. Rev. XLI. 410 The mechanism of excitation of the triplet state..involves an intersystem ‘crossing’ of potential curves for the 1Γ* and 3Γ states.1951Discussions Faraday Soc. IX. 15 Intersystem crossing is the spin-orbit-coupling-dependent internal conversion.1965Jrnl. Chem. Physics XLIII. 2132/1 The absolute rate of intersystem crossing by excited singlets of triphenylene must be a couple of orders of magnitude faster than the same process in naphthalene.1978P. W. Atkins Physical Chem. xviii. 596 Singlet to triplet switching is called intersystem crossing.
“intersystem”的英文意思

 

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